Lesson 6: Reduction and Refining of Metals
This lesson details the processes used to convert the concentrated ore into crude metal and then purify it.
- Calcination and Roasting: These are two thermal processes used to convert the concentrated ore into a more reactive form. Calcination involves heating a carbonate or hydroxide ore in the absence of air, while roasting involves heating a sulfide ore in the presence of air.
- Reduction: The main reduction processes are:
- Smelting: This uses a reducing agent like carbon or carbon monoxide to reduce the metal oxide. The process is carried out in a furnace at high temperatures.
- Electrolytic Reduction: This method is used for highly electropositive metals like aluminum and alkali metals, which cannot be reduced by carbon. The metal is extracted from its molten ore by electrolysis.
- Refining: The refining of crude metals can be done by several methods:
- Distillation: Used for low boiling point metals like zinc and mercury.
- Liquation: Used for metals with low melting points, like tin and lead.
- Electrolytic Refining: This is a very common method for purifying metals like copper and silver. The impure metal acts as the anode, and a pure strip of the same metal acts as the cathode.
- Vapour Phase Refining: This involves converting the metal into a volatile compound, which is then decomposed to give the pure metal. Examples include the Mond’s process for nickel and the van Arkel process for zirconium and titanium.
