Lesson 1: General Principles of Metallurgy
This lesson lays the groundwork for the entire chapter by defining key terms and outlining the overall process of extracting metals from their natural sources.
- Ores and Minerals: A mineral is a naturally occurring inorganic solid with a definite chemical composition. An ore is a mineral from which a metal can be extracted profitably. Not all minerals are ores. For example, bauxite () is the main ore of aluminum.
- Gangue: This refers to the unwanted, rocky, or earthy impurities associated with an ore. The process of removing the gangue is known as concentration or ore dressing.
- Thermodynamics of Reduction: The principle behind metallurgy is that a metal oxide must be reduced to its metallic form. The feasibility of this reduction is determined by the Gibbs free energy change (). For a reaction to be spontaneous, must be negative. The Ellingham diagram is a graphical representation of the Gibbs free energy change for the formation of various oxides at different temperatures, which helps in choosing the most suitable reducing agent for a particular metal oxide. A reducing agent is effective if the line for its oxidation lies below the line for the metal oxide’s reduction on the diagram.
