Lesson 3: Isomerism in Coordination Compounds
This lesson explores the different ways in which coordination compounds can have the same molecular formula but different arrangements of atoms.
- Structural Isomerism: This type of isomerism arises from differences in the bonds within the coordination entity.
- Ionization Isomerism: Isomers that produce different ions in solution. For example, and .
- Hydrate Isomerism: Isomers that differ in the number of water molecules inside and outside the coordination sphere.
- Linkage Isomerism: Occurs with ambidentate ligands (ligands that can bond through different donor atoms), such as (nitro) and (nitrito).
- Stereoisomerism: This type of isomerism involves the same bonds but different spatial arrangements.
- Geometrical Isomerism (cis-trans): This is common in complexes with coordination numbers 4 and 6. For example, in a square planar complex like , the ligands can be adjacent (cis) or opposite (trans).
- Structural Isomerism: This type of isomerism arises from differences in the bonds within the coordination entity.
* **Optical Isomerism**: Occurs when a coordination compound is non-superimposable