Lesson 4: Refining of Metals
This final lesson covers the various processes used to purify the crude metal obtained after the reduction step.
- Distillation: Used for refining low boiling point metals like zinc and mercury. The impure metal is heated to its boiling point and then condensed to collect the pure metal.
- Liquation: This method is used for metals with low melting points, such as tin and lead. The impure metal is heated on a sloping hearth, where the pure metal melts and flows away, leaving the solid impurities behind.
- Electrolytic Refining: This is one of the most common and effective methods for purifying metals like copper and silver. An impure metal rod serves as the anode, and a thin strip of pure metal serves as the cathode. Upon passing an electric current, the impure metal at the anode dissolves and is deposited as pure metal on the cathode.
- Vapour Phase Refining: This method involves converting the impure metal into a volatile compound, which is then decomposed at a higher temperature to obtain the pure metal. Two important examples are the Mond’s process for nickel and the van Arkel process for zirconium and titanium.
- Zone Refining: This is an extremely effective method for obtaining ultra-pure metals (like semiconductors). A mobile heater moves along a rod of impure metal, causing a small molten zone. As the heater moves, the pure metal crystallizes out, and the impurities are carried along with the molten zone.
